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Chemistry of Acidic and Neutralized Alum Shale Pit Lakes 50 Years After Mine Closure, Kvarntorp, Sweden
Örebro universitet, Institutionen för naturvetenskap och teknik. (Man-Technology-Environment Research Centre (MTM))ORCID-id: 0000-0002-7680-1117
Örebro universitet, Institutionen för naturvetenskap och teknik. (Man-Technology-Environment Research Centre (MTM))ORCID-id: 0000-0001-7845-6495
Institute of Geoscience, Friedrich Schiller University, Jena, Germany.
Örebro universitet, Institutionen för naturvetenskap och teknik. Remedy by Sweden AB, Eskilstuna, Sweden. (Man-Technology-Environment Research Centre (MTM))ORCID-id: 0000-0002-2104-4593
Vise andre og tillknytning
2020 (engelsk)Inngår i: Mine Water and the Environment, ISSN 1025-9112, E-ISSN 1616-1068, Vol. 39, nr 3, s. 481-497Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Several large pits were left after alum shale was mined from 1942 to 1966 in the Kvarntorp area of Sweden. Of these, the pit lakes Polen and Norrtorpssjon are the focus of this study. They have elevated levels of Na, K, Mg, Ca, Al, Mn, Fe, and sulphate, as well as trace elements, from weathering of the exposed shale. Both lakes had a stable pH below 4 until 1996 when the pH in Norrtorpssjon started to increase, exceeding 8 in 2010, due to inflow of leachates from alkaline waste dumped in an adjacent waste deposit, similar to a large scale anoxic limestone drain (ALD). Iron and Al concentrations decreased as the pH increased, indicating formation of particulate species which accumulate as sediments. The Co, Ni, and Zn concentrations also decreased, probably due to association with the solid phases, while Cu was less affected by the increase in pH, possibly due to formation of complexes with dissolved organic matter. Vanadium concentrations show limited solubility, while Mo concentrations increased at higher pH. Uranium concentrations decreased from above 80 mu g/L to below 10 mu g/L before rising to 30-35 mu g/L due to the formation of soluble carbonate complexes at higher pH levels. The elevated levels of Li, Sr, and U indicate that weathering has continued despite the pH change. Both pit lakes are stratified, but no seasonal overturn has been observed. Long-term behaviour of this large-scale ALD and its implications are also discussed.

sted, utgiver, år, opplag, sider
Springer, 2020. Vol. 39, nr 3, s. 481-497
Emneord [en]
Weathering, Leachate, Sediment, Vanadium, Molybdenum, Uranium
HSV kategori
Identifikatorer
URN: urn:nbn:se:oru:diva-80750DOI: 10.1007/s10230-020-00665-yISI: 000516394800001Scopus ID: 2-s2.0-85080921121OAI: oai:DiVA.org:oru-80750DiVA, id: diva2:1415966
Merknad

Funding Agencies:

Örebro University  

SAKAB-Kumla Foundation  

Tilgjengelig fra: 2020-03-20 Laget: 2020-03-20 Sist oppdatert: 2020-12-16bibliografisk kontrollert
Inngår i avhandling
1. Environmental impact of alum shale mining in Kvarntorp, Närke, Sweden
Åpne denne publikasjonen i ny fane eller vindu >>Environmental impact of alum shale mining in Kvarntorp, Närke, Sweden
2020 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

Due to scarcity of imported liquid fuel during World War II, alum shale was mined for oil production in the Kvarntorp area 1942-1966. The shale contains both organic matter (kerogen) and elevated concentrations of trace elements such as molybdenum, nickel, uranium and vanadium. Today there are several pit lakes in the area and a 100-meter-high waste deposit, Kvarntorpshögen, consisting mostly of crushed and burned shale but also some unburned crushed shale and lime waste.

The aim of this study was to get a better understanding of the environmental impact of alum shale mining with focus on trace metal release. During the production era, the surroundings were highly affected by both sulphur rich flue gas emissions and bad water quality in downstream waters. The former mining activities show impact also today, with higher concentrations in downstream water than upstream the area. Analyses and leaching tests of solid samples have shown pyrite weathering in shale and unburned shale waste with release of for example nickel and uranium.

Analyses of groundwater in eleven wells around the deposit show ongoing leaching of both shale waste generating a circumneutral leachate and unprocessed shale leading to acidic leachates.

All pit lakes in contact with alum shale waste or the shale horizon show elevated sulphate concentrations indicating pyrite weathering, although only one is still acidic today. Also Norrtorpssjön was acidic until a pH rise due to adjacent dumping of alkaline waste. The pH increase was followed by a decrease in aluminium, cobalt, magnesium and nickel.

Surface water analysis show that the waste deposit is estimated to contribute with less than a fifth of the mass transport whereas the western pit lakes contribute with the largest part.

sted, utgiver, år, opplag, sider
Örebro: Örebro University, 2020. s. 80
Serie
Örebro Studies in Chemistry, ISSN 1651-4270 ; 27
Emneord
alum shale, black shale, oil shale, Kvarntorp, uranium, surface water, groundwater, open pits
HSV kategori
Identifikatorer
urn:nbn:se:oru:diva-87667 (URN)978-91-7529-362-2 (ISBN)
Disputas
2021-01-08, Örebro universitet, Forumhuset, Hörsal F, Fakultetsgatan 1, Örebro, 09:15 (engelsk)
Opponent
Veileder
Tilgjengelig fra: 2020-11-27 Laget: 2020-11-27 Sist oppdatert: 2020-12-18bibliografisk kontrollert

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Åhlgren, KristinaSjöberg, ViktorAllard, BertBäckström, Mattias

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