To Örebro University

oru.seÖrebro University Publications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Chemistry of Acidic and Neutralized Alum Shale Pit Lakes 50 Years After Mine Closure, Kvarntorp, Sweden
Örebro University, School of Science and Technology. (Man-Technology-Environment Research Centre (MTM))ORCID iD: 0000-0002-7680-1117
Örebro University, School of Science and Technology. (Man-Technology-Environment Research Centre (MTM))ORCID iD: 0000-0001-7845-6495
Institute of Geoscience, Friedrich Schiller University, Jena, Germany.
Örebro University, School of Science and Technology. Remedy by Sweden AB, Eskilstuna, Sweden. (Man-Technology-Environment Research Centre (MTM))ORCID iD: 0000-0002-2104-4593
Show others and affiliations
2020 (English)In: Mine Water and the Environment, ISSN 1025-9112, E-ISSN 1616-1068, Vol. 39, no 3, p. 481-497Article in journal (Refereed) Published
Abstract [en]

Several large pits were left after alum shale was mined from 1942 to 1966 in the Kvarntorp area of Sweden. Of these, the pit lakes Polen and Norrtorpssjon are the focus of this study. They have elevated levels of Na, K, Mg, Ca, Al, Mn, Fe, and sulphate, as well as trace elements, from weathering of the exposed shale. Both lakes had a stable pH below 4 until 1996 when the pH in Norrtorpssjon started to increase, exceeding 8 in 2010, due to inflow of leachates from alkaline waste dumped in an adjacent waste deposit, similar to a large scale anoxic limestone drain (ALD). Iron and Al concentrations decreased as the pH increased, indicating formation of particulate species which accumulate as sediments. The Co, Ni, and Zn concentrations also decreased, probably due to association with the solid phases, while Cu was less affected by the increase in pH, possibly due to formation of complexes with dissolved organic matter. Vanadium concentrations show limited solubility, while Mo concentrations increased at higher pH. Uranium concentrations decreased from above 80 mu g/L to below 10 mu g/L before rising to 30-35 mu g/L due to the formation of soluble carbonate complexes at higher pH levels. The elevated levels of Li, Sr, and U indicate that weathering has continued despite the pH change. Both pit lakes are stratified, but no seasonal overturn has been observed. Long-term behaviour of this large-scale ALD and its implications are also discussed.

Place, publisher, year, edition, pages
Springer, 2020. Vol. 39, no 3, p. 481-497
Keywords [en]
Weathering, Leachate, Sediment, Vanadium, Molybdenum, Uranium
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:oru:diva-80750DOI: 10.1007/s10230-020-00665-yISI: 000516394800001Scopus ID: 2-s2.0-85080921121OAI: oai:DiVA.org:oru-80750DiVA, id: diva2:1415966
Note

Funding Agencies:

Örebro University  

SAKAB-Kumla Foundation  

Available from: 2020-03-20 Created: 2020-03-20 Last updated: 2020-12-16Bibliographically approved
In thesis
1. Environmental impact of alum shale mining in Kvarntorp, Närke, Sweden
Open this publication in new window or tab >>Environmental impact of alum shale mining in Kvarntorp, Närke, Sweden
2020 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Due to scarcity of imported liquid fuel during World War II, alum shale was mined for oil production in the Kvarntorp area 1942-1966. The shale contains both organic matter (kerogen) and elevated concentrations of trace elements such as molybdenum, nickel, uranium and vanadium. Today there are several pit lakes in the area and a 100-meter-high waste deposit, Kvarntorpshögen, consisting mostly of crushed and burned shale but also some unburned crushed shale and lime waste.

The aim of this study was to get a better understanding of the environmental impact of alum shale mining with focus on trace metal release. During the production era, the surroundings were highly affected by both sulphur rich flue gas emissions and bad water quality in downstream waters. The former mining activities show impact also today, with higher concentrations in downstream water than upstream the area. Analyses and leaching tests of solid samples have shown pyrite weathering in shale and unburned shale waste with release of for example nickel and uranium.

Analyses of groundwater in eleven wells around the deposit show ongoing leaching of both shale waste generating a circumneutral leachate and unprocessed shale leading to acidic leachates.

All pit lakes in contact with alum shale waste or the shale horizon show elevated sulphate concentrations indicating pyrite weathering, although only one is still acidic today. Also Norrtorpssjön was acidic until a pH rise due to adjacent dumping of alkaline waste. The pH increase was followed by a decrease in aluminium, cobalt, magnesium and nickel.

Surface water analysis show that the waste deposit is estimated to contribute with less than a fifth of the mass transport whereas the western pit lakes contribute with the largest part.

Place, publisher, year, edition, pages
Örebro: Örebro University, 2020. p. 80
Series
Örebro Studies in Chemistry, ISSN 1651-4270 ; 27
Keywords
alum shale, black shale, oil shale, Kvarntorp, uranium, surface water, groundwater, open pits
National Category
Other Chemistry Topics
Identifiers
urn:nbn:se:oru:diva-87667 (URN)978-91-7529-362-2 (ISBN)
Public defence
2021-01-08, Örebro universitet, Forumhuset, Hörsal F, Fakultetsgatan 1, Örebro, 09:15 (English)
Opponent
Supervisors
Available from: 2020-11-27 Created: 2020-11-27 Last updated: 2020-12-18Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Åhlgren, KristinaSjöberg, ViktorAllard, BertBäckström, Mattias

Search in DiVA

By author/editor
Åhlgren, KristinaSjöberg, ViktorAllard, BertBäckström, Mattias
By organisation
School of Science and Technology
In the same journal
Mine Water and the Environment
Environmental Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 315 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf