Direct determination of the absolute configuration of a cyclic thiolsulfinate by VCD spectroscopy
2003 (English)In: Tetrahedron: asymmetry, ISSN 0957-4166, E-ISSN 1362-511X, Vol. 14, no 15, p. 2267-2269Article in journal (Refereed) Published
Abstract [en]
Experimental and calculated vibrational circular dichroism (VCD) spectra of the enantiomers of the conformationally rigid thiolsulfinate, naphtho[1,8-cd]-1,2-dithiole 1-oxide 1, obtained by chromatographic resolution of the racemate, were in excellent agreement, showing a (+)-(S)-1/(-)-(R)-1 relationship.
Place, publisher, year, edition, pages
Pergamon Press, 2003. Vol. 14, no 15, p. 2267-2269
Keywords [en]
thiosulfinic acid derivative, article, assay, chromatography, circular dichroism, enantiomer, infrared radiation, priority journal
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:oru:diva-82390DOI: 10.1016/S0957-4166(03)00405-1ISI: 000184619100021Scopus ID: 2-s2.0-0041698088OAI: oai:DiVA.org:oru-82390DiVA, id: diva2:1434857
2020-06-042020-06-042020-06-04Bibliographically approved