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Phosphorus speciation in sewage sludge and their ashes after incineration as a function of treatment processes
Örebro University, School of Science and Technology. Fortum Waste Solutions AB, Kumla, Sweden. (MTM Research Centre,)ORCID iD: 0000-0003-2962-6587
Örebro University, School of Science and Technology. (MTM Research Centre)ORCID iD: 0000-0001-9960-0070
Örebro University, School of Science and Technology. (MTM Research Centre)ORCID iD: 0000-0002-2104-4593
Fortum Waste Solutions AB, Kumla, Sweden.
2024 (English)In: Waste Management & Research, ISSN 0734-242X, E-ISSN 1096-3669, article id 734242X241252913Article in journal (Refereed) Epub ahead of print
Abstract [en]

Phosphorus (P) is a key component in agricultural fertilizers, but it is also a scarce resource, why its recycling has been thoroughly investigated and one promising resources is sewage sludge. Because of stricter regulations in terms of sludge disposal, thermal treatment (e.g. incineration) has become an attractive option. The incineration process alters the chemical speciation of P in favour to calcium-associated (apatite, apatite phosphorus (AP)) species, which is preferred for P recovery. In order to achieve qualitatively transformation, it is important to identify limiting or promoting factors. This study reports on the impact of iron, aluminium and calcium on the transformation of iron- and aluminium-phosphate (NAIP) to AP species, assessed by studying sludge and ash from 10 municipal wastewater treatment plants in Sweden. The effect of iron and aluminium added in the treatment processes was also evaluated. The obtained results show that high calcium concentration favours formation of AP species in both sludge and ashes, whereas high concentration of iron and aluminium favours formation of NAIP species in the sludge. The transformation from NAIP to AP species is hampered by aluminium, irrespectively of its origin, whereas no such correlations could be seen for iron. Therefore, in order to enable efficient P recovery from sewage sludge ash, the amount of aluminium added in the treatment process, as well as its concentration in influent streams to the treatment plants, must be limited.

Place, publisher, year, edition, pages
Sage Publications, 2024. article id 734242X241252913
Keywords [en]
Sewage sludge, aluminium, apatite, incineration, phosphorus, recirculation, speciation, sustainability
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:oru:diva-114002DOI: 10.1177/0734242X241252913ISI: 001236459300001PubMedID: 38819926OAI: oai:DiVA.org:oru-114002DiVA, id: diva2:1864088
Available from: 2024-06-03 Created: 2024-06-03 Last updated: 2024-06-12Bibliographically approved

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Nilsson, CharlotteKarlsson, StefanAllard, Bert

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