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Neutralisation of an acidic pit lake by alkaline waste products
Örebro University, School of Science and Technology. (MTM Biogeosphere Dynamics)ORCID iD: 0000-0002-2104-4593
Örebro University, School of Science and Technology. (MTM Biogeosphere Dynamics)ORCID iD: 0000-0002-2674-4994
Örebro University, School of Science and Technology. (MTM Biogeosphere Dynamics)ORCID iD: 0000-0001-9960-0070
Institute of Geoscience, Friedrich Schiller University, Jena, Germany .
2014 (English)In: Environmental Science and Pollution Research, ISSN 0944-1344, E-ISSN 1614-7499, Vol. 21, no 11, p. 6930-6938Article in journal (Refereed) Published
Abstract [en]

A former open pit where black shale (alum shale) was excavated during 1942-1965 has been water filled since 1966. The water chemistry was dominated by calcium and sulphate and had a pH of 3.2-3.4 until 1997-1998, when pH was gradually increasing. This was due to the intrusion of leachates from alkaline cement waste deposited close to the lake. A stable pH of around 7.5 was obtained after 6-7 years. The chemistry of the pit lake has changed due to the neutralisation. Concentrations of some dissolved metals, notably zinc and nickel, have gone down, as a result of adsorption/co-precipitation on solid phases (most likely iron and aluminium hydroxides), while other metals, notably uranium and molybdenum, are present at elevated levels. Uranium concentration is reaching a minimum of around pH 6.5 and is increasing at higher pH, which may indicate a formation of neutral and anionic uranyl carbonate species at high pH (and total carbonate levels around 1 mM). Weathering of the water-exposed shale is still in progress.

Place, publisher, year, edition, pages
Springer, 2014. Vol. 21, no 11, p. 6930-6938
Keywords [en]
Alum shale; Black shale; Liming; Neutralisation; Pit lake
National Category
Earth and Related Environmental Sciences
Research subject
Enviromental Science
Identifiers
URN: urn:nbn:se:oru:diva-40744DOI: 10.1007/s11356-013-2026-xISI: 000336371000015PubMedID: 23913161Scopus ID: 2-s2.0-84901276811OAI: oai:DiVA.org:oru-40744DiVA, id: diva2:778582
Available from: 2015-01-11 Created: 2015-01-11 Last updated: 2025-02-07Bibliographically approved

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Allard, BertBäckström, MattiasKarlsson, Stefan

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