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Chemical characterization of green liquor dregs from 16 Swedish pulp and paper mills between 2017 and 2019
Örebro universitet, Institutionen för naturvetenskap och teknik. (Man-Technology-Environment Research Centre)ORCID-id: 0009-0001-7574-7542
Örebro universitet, Kommunikation och samverkansstöd. Bergskraft Bergslagen AB, Kumla, Sweden. (Man-Technology-Environment Research Centre)ORCID-id: 0000-0001-9348-6481
Örebro universitet, Institutionen för naturvetenskap och teknik. Bergskraft Bergslagen AB, Kumla, Sweden. (Man-Technology-Environment Research Centre)ORCID-id: 0000-0002-2674-4994
2024 (engelsk)Inngår i: Environmental Science and Pollution Research, ISSN 0944-1344, E-ISSN 1614-7499, Vol. 31, nr 32, s. 45011-45034Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Green liquor dregs (GLD) is an alkaline by-product from the pulp and paper industry with a pH between 10 and 14. Today most of the produced GLD in Sweden is landfilled. As a fine-grained alkaline material, it might be possible to use it for acid-generating mining waste remediation. To increase the utilization, quality characteristics and environmental performance need to be determined. In this study samples were collected 5 times from 16 mills during a period of 2.5 years, and were characterized by analyzing dry matter content, loss on ignition (LOI) 550 °C and LOI 950 °C, elemental analysis, pH, electrical conductivity, and calorific value. The results were then evaluated using multivariate statistics (PCA) as well as being compared to other studies and Swedish till. The results show that even if GLD is heterogenous (both within a mill and between different mills) trends can be seen for samples from most mills. When samples do stand out, it is predominately related to the same four mills. Most of the studied parameters showed characteristics favorable for use as a remediant; however, TOC, sulfur, and some of the elements require further study. In general, this study concludes that GLD can be a viable option for the remediation of small orphaned sulfidic mining sites and thus worthy of further studies on the interaction between GLD and acidic mining waste.Overall, GLD can be a good alternative for cost-effective remediation of smaller orphaned mining sites. It is readily available in large quantities, has the qualities needed for remediation of many orphaned acidic mining sites, and can often be locally sourced near the mining site. The use of GLD for mining site remediation is likely also a more sustainable method compared to traditional remediation methods.

sted, utgiver, år, opplag, sider
Springer, 2024. Vol. 31, nr 32, s. 45011-45034
Emneord [en]
Acid mine drainage, Acid rock drainage, Co-disposal, Green liquor dregs, Mine site remediation mine site reclamation, Mine waste, Paper pulp industry, Remediation
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URN: urn:nbn:se:oru:diva-114611DOI: 10.1007/s11356-024-34074-3PubMedID: 38961019Scopus ID: 2-s2.0-85197454155OAI: oai:DiVA.org:oru-114611DiVA, id: diva2:1881868
Forskningsfinansiär
Örebro UniversityMistra - The Swedish Foundation for Strategic Environmental Research, DIA 2013/036Tilgjengelig fra: 2024-07-04 Laget: 2024-07-04 Sist oppdatert: 2025-01-07bibliografisk kontrollert

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