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Estimating Release of Trace Elements from an Area with Historical Open Pit Mining of Alum Shale Using Mass Transport and Element/Sulfate Ratios Calculations
Örebro universitet, Institutionen för naturvetenskap och teknik. (Man-Technology-Environment Research Centre (MTM))ORCID-id: 0000-0002-7680-1117
Örebro universitet, Institutionen för naturvetenskap och teknik. (Man-Technology-Environment Research Centre (MTM))ORCID-id: 0000-0001-7845-6495
Örebro universitet, Institutionen för naturvetenskap och teknik. (Man-Technology-Environment Research Centre (MTM))ORCID-id: 0000-0002-2674-4994
2020 (Engelska)Ingår i: Environments, E-ISSN 2076-3298, Vol. 7, nr 11, artikel-id 100Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Alum shale was mined for oil and uranium production in Kvarntorp, Sweden, 1942-1966. Remnants such as pit lakes, exposed shale and a 100-meter-high waste deposit with a hot interior affect the surrounding environment, with elevated concentrations of, e.g., Mo, Ni and U in the recipient. Today most pit lakes are circumneutral while one of the lakes is still acidic. All pit lakes show signs of sulfide weathering with elevated sulfate concentrations. Mass transport calculations show that for elements such as uranium and molybdenum the western lake system (lake Soderhavet in particular) contributes the largest part. For sulfate, the two western lakes contribute with a quarter each, the eastern lake Norrtorpssjon about a third and a serpentine pond system receiving water from the waste deposit contributes around 17%. Except for a few elements (e.g., nickel 35%), the Serpentine system (including the waste deposit area) is not a very pronounced point source for metal release compared to the pit lakes. Estimates about future water runoff when the deposit has cooled down suggest only a slight increase in downstream water flow. There could possibly be first flush effects when previous hot areas have been reached by water.

Ort, förlag, år, upplaga, sidor
MDPI , 2020. Vol. 7, nr 11, artikel-id 100
Nyckelord [en]
alum shale, black shale, Kvarntorp, trace elements, sulfate, weathering, uranium
Nationell ämneskategori
Miljövetenskap
Identifikatorer
URN: urn:nbn:se:oru:diva-88063DOI: 10.3390/environments7110100ISI: 000592812100001Scopus ID: 2-s2.0-85097077569OAI: oai:DiVA.org:oru-88063DiVA, id: diva2:1509995
Tillgänglig från: 2020-12-15 Skapad: 2020-12-15 Senast uppdaterad: 2023-02-20Bibliografiskt granskad
Ingår i avhandling
1. Environmental impact of alum shale mining in Kvarntorp, Närke, Sweden
Öppna denna publikation i ny flik eller fönster >>Environmental impact of alum shale mining in Kvarntorp, Närke, Sweden
2020 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Due to scarcity of imported liquid fuel during World War II, alum shale was mined for oil production in the Kvarntorp area 1942-1966. The shale contains both organic matter (kerogen) and elevated concentrations of trace elements such as molybdenum, nickel, uranium and vanadium. Today there are several pit lakes in the area and a 100-meter-high waste deposit, Kvarntorpshögen, consisting mostly of crushed and burned shale but also some unburned crushed shale and lime waste.

The aim of this study was to get a better understanding of the environmental impact of alum shale mining with focus on trace metal release. During the production era, the surroundings were highly affected by both sulphur rich flue gas emissions and bad water quality in downstream waters. The former mining activities show impact also today, with higher concentrations in downstream water than upstream the area. Analyses and leaching tests of solid samples have shown pyrite weathering in shale and unburned shale waste with release of for example nickel and uranium.

Analyses of groundwater in eleven wells around the deposit show ongoing leaching of both shale waste generating a circumneutral leachate and unprocessed shale leading to acidic leachates.

All pit lakes in contact with alum shale waste or the shale horizon show elevated sulphate concentrations indicating pyrite weathering, although only one is still acidic today. Also Norrtorpssjön was acidic until a pH rise due to adjacent dumping of alkaline waste. The pH increase was followed by a decrease in aluminium, cobalt, magnesium and nickel.

Surface water analysis show that the waste deposit is estimated to contribute with less than a fifth of the mass transport whereas the western pit lakes contribute with the largest part.

Ort, förlag, år, upplaga, sidor
Örebro: Örebro University, 2020. s. 80
Serie
Örebro Studies in Chemistry, ISSN 1651-4270 ; 27
Nyckelord
alum shale, black shale, oil shale, Kvarntorp, uranium, surface water, groundwater, open pits
Nationell ämneskategori
Annan kemi
Identifikatorer
urn:nbn:se:oru:diva-87667 (URN)978-91-7529-362-2 (ISBN)
Disputation
2021-01-08, Örebro universitet, Forumhuset, Hörsal F, Fakultetsgatan 1, Örebro, 09:15 (Engelska)
Opponent
Handledare
Tillgänglig från: 2020-11-27 Skapad: 2020-11-27 Senast uppdaterad: 2020-12-18Bibliografiskt granskad

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Åhlgren, KristinaSjöberg, ViktorBäckström, Mattias

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